Gmail uses some strange ports, including a requirement for a secure connection, probably to stop unsolicited relaying etc
The easiest way to get it working would be to upgrade to XP Professional and then install IIS which comes with an smtp server that would allow you send emails using the computer itself as opposed to an external gmail account.
in fact with a quick google serach i found this: www.softstack.com/freesmtp.html
this is a free smtp server that shopuld tun under XP Home.
1) Install this and setup
2) Set FM Server SMTP Server Address to 127.0.0.1
3) keep your email address as whatever you want including the previous gmail email address if you want. You could even have email@example.com://forum-en.filemaker.com/t5/user/viewprofilepage/user-id/3056
3) Click test SMTP Settings.
4) Should do the job!
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I have just been through what seems could be a similar problem. Turns out that our suite of Gmail addresses is part of Google Apps and an administrator has to tick the box on the Admin console. Having tracked down the administrator I now live in hope...
The admin console looks like this. The relevant option is circled in red.
The FMP window for setting up email from another SMTP server like this