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It has been a few years since i've used Captive (pre-Adobe) but i seem to recall a way to export the results of an assessment to XML. If that is still the case, you can perform an export at the end of the assessment. You would then need some script or mechanism to get the results over to a location where a server side script could then import the results.
Thanks Matt for your assistance, I was hoping that there would be a direct link or handshaking without the need for script.