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If I had to guess, when last the data file was closed, it was closed on a non-Classic layout. It's opening there before the OnFirstWindowOpen trigger can fire.
(The reason I suspect this is because it happened to me.)
I checked that. Also now there no non-classic layouts in either file
FMSA is running on Mountain Lion. I am beginning to think that is still not a good idea.
Definite head-scratcher. Was either file converted from .fp7?
Found the problem - all my fault. Too embarassed to explain !!
Okay, good. I won't ask; just glad you found it.