Yes, you can do this through scripting. The Add Account script step gives you this dialog:
Note: I generally recommend against developers knowing users' passwords. Industry practice is to use a generated password and force the user to change it the first time in. You can also automate that process through scripting.
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Yes, you can script adding, deleting, or changing accounts with the Accounts scripts:
You can specify the privilege set, too.
If you need to change an account name you can do that by deleting and re-adding an account. As the list only has the ability to change passwords, but not account names.