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Try changing your default PDF viewer from Preview to Acrobat or vice versa. Update both of them to make sure you have the latest version.
... well I haven't seen this problem mentioned before Mavericks... ;-)
Default PDF viewer now changed to Acrbat and it seems to work well. No problems up till now.
Set Acrobat as my default PDF viewer now and it seems to work. Probably nothing to do with Mavericks.